Ligand-assisted preparation of highly active and stable nanometric Pd confined catalysts for deep catalytic oxidation of toluene

摘要

In this study, mesoporous SBA-15 supported Pd catalysts were synthesized through impregnation and grafting approaches. Moreover, the influences of different solvents (ethanol, H(2)O, tetrahydrofuran, dimethyl sulphoxide and N,N-dimethylformamide) on the dispersion of supported Pd nanoparticles were also systematically investigated. The prepared materials were comprehensively explored by various techniques. including XRD, EDS, ICP-OES, H(2) chemisorption, N(2) adsorption/desorption, TG-DSC, FT-IR, TEM and STEM. It is found that the traditional impregnation method has some disadvantages in obtaining highly dispersed Pd active phase. Whereas, the grafting method could highly disperse Pd nanoparticles within the mesoporous channels of support material, and the grafting procedure should be promising in designing highly dispersed Pd particles on the silica-based mesoporous materials. The catalyst prepared via the grafting procedure possesses much higher activity and selectivity than that prepared by impregnation method for deep catalytic oxidation of toluene. (C) 2010 Elsevier B.V. All rights reserved.